クロマトグラフィー研究ジャーナル

Development of a Liquid Chromatographic Method Based On Ultraviolet-Visible and Electrospray Ionization Mass Spectrometric Detection for the Identification of Nitrocatechols and Related Tracers in Biomass Burning Atmospheric Organic Aerosol

Farhat Yasmeen, Zoran Ketanovski, Magda Claeys, Irina Girgik, and Cusak A

Examining the chemical composition of biomass burning vaporized (BBA) is exceptionally vital in arrange to evaluate their effect on the climate and the biosphere. Within the display think about, we center on the characterization of a few recently recognized biomass burning airborne tracers counting methyl nitrocatechols, nitroguaiacols and 4-nitrocatechol, but too on nitrophenols, methyl nitrophenols and nitrosalicylic acids, utilizing fluid chromatography pair mass spectrometry.

Nitrogen-containing natural compounds within the air have drawn consideration owing to their effect on airborne chemistry and material science and their potential antagonistic impacts on the biosphere. Among them, nitrocatechols and their homologs have as of late been related with biomass burning. Inside the show consider, nitrocatechols, nitrophenols, nitroguaiacols and nitrosalicylic acids (NSAs) were at the same time measured for the essential time by utilizing a unused informative technique based on liquid chromatography/tandem mass spectrometry, which was effectively optimized and endorsed. A few analyte particular issues with respect to the test planning and chromatographic investigation were tended to in arrange to guarantee strategy affectability, exactness, and precision. Test network impacts were altogether explored in arrange to guarantee strategy specificity. The strategy was found to be touchy with limits of location extending from 0.1 to 1.0 μg L(-1), and with exactness by and large between 90 and 104%.

The relative standard deviations for repeatability and middle of the road accuracy were way better than 4% and 9%, separately. The strategy was connected to the investigation of winter and summer PM(10) tests from the city of Ljubljana, Slovenia. Airborne concentrations as tall as 152 and 134 ng m(-3) were gotten for the major airborne nitro-aromatics: 4-nitrocatechol (4NC) and methyl-nitrocatechols (MNCs), individually. Up to 500-times higher concentrations of 4NC and MNCs were found in winter compared to summer mist concentrates. The relationship investigation for winter tests appeared that 4NC, MNCs, and NSAs are unequivocally inter-correlated (R(2)=0.84-0.96). Critical connections between these analytes and anhydrosugars back their proposed starting from biomass burning. The considered nitro-aromatics were found to constitute a non-negligible division (around 1%) of the common carbon.

Considering the chemical composition of biomass burning vaporized (BBA) is exceptionally critical in arrange to survey their effect on the climate and the biosphere. Within the display think about, we center on the characterization of a few recently recognized biomass burning vaporized tracers counting methyl nitrocatechols, nitroguaiacols and 4‐nitrocatechol, but moreover on nitrophenols, methyl nitrophenols and nitrosalicylic acids, utilizing fluid chromatography pair mass spectrometry.